Structure–Property Relationships in Hierarchically Ordered Self-Assembled Systems

The mechanical behavior of soft materials can be very challenging to measure accurately when using conventional measurements. NU-MRSEC researchers recently discovered a new hierarchically ordered system that is based on the co-assembly of high molecular weight polyanions and peptide amphiphiles at the interface of two aqueous solutions. These closed membranes (sacs) have a complex hierarchical structure, which presents a unique challenge in quantifying its mechanical properties. Membrane inflation and drop shape analysis techniques have been used to quantitatively characterize the membrane properties. These findings will be essential for tailoring the membrane characteristics for specific future applications.

pa sac

SEM image of a sac made of 2 wt % alginate and 2 wt % peptide amphiphile.

 

Ronit Bitton, Daniel Carvajal, Jason Mantei, Yuri Velichko, Kenneth R. Shull, Samuel I. Stupp

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The Materials Research Science and Engineering Center (MRSEC) is supported by the National Science Foundation under NSF Award Number DMR-0520513. Any opinions, findings and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect those of the National Science Foundation.
© 2008 Northwestern University